Enviar artigo por via de e-mail SYNTHESIS AND STRUCTURE OF NEW [5]FERROCENOPHANE
- Autores: Medved’ko A.V.1, Churakov A.V.2, Krut’ko D.P.3, Vatsadze S.Z.1
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Afiliações:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Department of Chemistry, Lomonosov Moscow State University
- Edição: Volume 513, Nº 1 (2023)
- Páginas: 62-66
- Seção: CHEMISTRY
- URL: https://rjeid.com/2686-9535/article/view/651932
- DOI: https://doi.org/10.31857/S2686953523600095
- EDN: https://elibrary.ru/CCEEDQ
- ID: 651932
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Resumo
The first example of intramolecular diastereoselective domino reaction of ferrocene 1,1'-bis-enone to [5]ferrocenophane initiated with sodium ethylate was found. The product is [5]ferrocenophane with two pyridyl and one ethoxy substituents arranged asymmetrically in five carbon bridge. Diffraction studies showed that ferrocene is in almost ideal eclipsed conformation. The fan conformation found in the crystal is also preserved in solution, which was determined by NMR spectroscopy.
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Sobre autores
A. Medved’ko
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: zurabych@gmail.com
Russian Federation, 119991
A. Churakov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zurabych@gmail.com
Russian Federation, 119991
D. Krut’ko
Department of Chemistry, Lomonosov Moscow State University
Email: zurabych@gmail.com
Russian Federation, 119991
S. Vatsadze
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: zurabych@gmail.com
Russian Federation, 119991
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