SINGLE-, DOUBLE- AND MULTI-WALLED CARBON NANOTUBES AS ELECTRICALLY CONDUCTIVE ADDITIVES IN LITHIUM-ION BATTERY CATHODES

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The paper presents a comparative study of the characteristics of lithium iron phosphate positive electrodes with various types of commercially available carbon nanotubes – single-walled (SWCNT), double-walled (DWCNT) and multi-walled (MWCNT). Electrochemical characteristics of the cathode materials were investigated using electrochemical impedance spectroscopy and galvanostatic charge/discharge measurements. Cyclic stability at various current densities was estimated. The best electrochemical characteristics are exhibited by cathode materials with SWCNT (advantage over DWCNT at discharge rates higher than 10C) and DWCNT (advantage over SWCNT during prolonged cycling). During cycling at a current density of 1C, the greatest loss of capacity was demonstrated by the MWCNT-based electrode. At the same time, the electrodes with SWCNT and DWCNT demonstrated satisfactory capacity retention after 50 charge/discharge cycles: over 94 and over 98%, respectively.

Авторлар туралы

A. Babkin

Department of Chemistry, Lomonosov Moscow State University

Хат алмасуға жауапты Автор.
Email: A.V.Babkin93@yandex.ru
Russian, 119991, Moscow

A. Kubarkov

Department of Chemistry, Lomonosov Moscow State University

Email: evgeny.antipov@gmail.com
Russian, 119991, Moscow

O. Drozhzhin

Department of Chemistry, Lomonosov Moscow State University

Email: evgeny.antipov@gmail.com
Russian, 119991, Moscow

S. Urvanov

Technological Institute for Superhard and Novel Carbon Materials

Email: evgeny.antipov@gmail.com
Russian, 108840, Troitsk, Moscow

I. Filimonenkov

Technological Institute for Superhard and Novel Carbon Materials

Email: evgeny.antipov@gmail.com
Russian, 108840, Troitsk, Moscow

A. Tkachev

Tambov State Technical University

Email: evgeny.antipov@gmail.com
Russian, 392000, Tambov

V. Mordkovich

Technological Institute for Superhard and Novel Carbon Materials

Email: evgeny.antipov@gmail.com
Russian, 108840, Troitsk, Moscow

V. Sergeyev

Department of Chemistry, Lomonosov Moscow State University

Email: evgeny.antipov@gmail.com
Russian, 119991, Moscow

E. Antipov

Department of Chemistry, Lomonosov Moscow State University; Skolkovo Institute of Science and Technology

Хат алмасуға жауапты Автор.
Email: evgeny.antipov@gmail.com
Russian, 119991, Moscow; Russian, 121205, Moscow

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Қосымша файлдар


© А.В. Бабкин, А.В. Кубарьков, О.А. Дрожжин, С.А. Урванов, И.С. Филимоненков, А.Г. Ткачев, В.З. Мордкович, В.Г. Сергеев, Е.В. Антипов, 2023