Inion Sulfocation Membranes Plasticized with Propylene Carbonate

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Abstract

The rapidly developing field of portable energy sources requires the search and development of effective materials for such devices. To improve the safety of the most common metal-ion batteries (lithium- and sodium-ion), instead of a liquid electrolyte, it is proposed to use a gel-polymer electrolyte with unipolar conductivity based on a Nafion-like electrolyte (Inion), plasticized with aprotic solvents. The work presents the results of a study of the thermal stability, molecular structure and supramolecular packing, as well as ionic conductivity of the Inion membrane in lithium and sodium forms, plasticized with propylene carbonate, using methods of simultaneous thermal analysis, IR spectroscopy, small-angle X-ray scattering and impedance spectroscopy.

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About the authors

R. R. Kayumov

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: shmygleval@mail.ru
Russian Federation, Chernogolovka

A. A. Lochina

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences; Moscow Institute of Physics and Technology (National Research University)

Email: shmygleval@mail.ru
Russian Federation, Chernogolovka; Dolgoprudny

A. N. Lapshin

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: shmygleval@mail.ru
Russian Federation, Chernogolovka

A. V. Bakirov

Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences; Kurchatov Institute

Email: shmygleval@mail.ru
Russian Federation, Moscow; Moscow

L. V. Shmygleva

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: shmygleval@mail.ru
Russian Federation, Chernogolovka

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Supplementary files

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2. Fig. 1. CTA and ionic current curves of Li-Inion (a) and Li-Inion/PC samples (b); TGA curves of Inion membrane in lithium and sodium forms (c)

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3. Fig. 2. Overview IR NIR spectra of Inion and Nafion membranes (a) and contours of the ν(SO) and ν(CF2) oscillation bands (b)

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4. Fig. 3. MURR curves: (a) original curves of H-Inion and kapton; (b) curves of Inion samples in different cationic forms taking into account kapton

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5. Fig. 4. (a) Equivalent scheme of impedance spectra: Rm - sample resistance, Cg - geometric capacitance of the measuring cell, ZW - Warburg element; (b) and (c) Impedance hodographs at different temperatures (points - experimental data, lines - approximation of impedance spectra by the equivalent scheme); (d) temperature dependences of specific ionic conductivity, geometric capacitance and dielectric permittivity of Na-ion/PC

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