The effect of surface treatment of composite polypropylene fibers on their properties

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Abstract

Composite materials containing zinc sulfide nanoparticles on the surface of microgranules of ultrafine polytetrafluoroethylene were obtained by thermal decomposition. The obtained materials were used to modify polypropylene fibers. The obtained filaments were examined by X-ray phase analysis and electron microscopy. Their mechanical and antibacterial properties have been studied. The particle sizes range from 7 to 30 nm. The application of the modifier makes the manifestation of edge defects less noticeable, which has a positive effect on their mechanical properties, such as modulus of elasticity and tensile strength. In addition, modification of polypropylene fibers leads to an increase in the antimicrobial properties of the modified thread.

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About the authors

V. E. Kirillov

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences; Center of the National Technological Initiative “Digital Materials Science: New Materials and Substances” Bauman Moscow State Technical University

Author for correspondence.
Email: kirillovladislav@gmail.com
Russian Federation, Moscow; Moscow

G. Y. Yurkov

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kirillovladislav@gmail.com
Russian Federation, Moscow

N. P. Prorokova

Krestov Institute of Solution Chemistry of the Russian Academy of Sciences; Ivanovo State Polytechnic University

Email: kirillovladislav@gmail.com
Russian Federation, Ivanovo; Ivanovo

S. Y. Vavilova

Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

Email: kirillovladislav@gmail.com
Russian Federation, Ivanovo

A. A. Ashmarin

A. A. Baykov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences

Email: kirillovladislav@gmail.com
Russian Federation, Moscow

V. I. Solodilov

N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences; Center of the National Technological Initiative “Digital Materials Science: New Materials and Substances” Bauman Moscow State Technical University

Email: kirillovladislav@gmail.com
Russian Federation, Moscow; Moscow

A. S. Voronov

The Joint Stock Company State Research Center Of The Russian Federation Troitsk Institute For Innovation And Fusion Research

Email: kirillovladislav@gmail.com
Russian Federation, Moscow, Troitsk

D. A. Zvyagintsev

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: kirillovladislav@gmail.com
Russian Federation, Moscow

V. M. Buznik

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: kirillovladislav@gmail.com
Russian Federation, Moscow

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Supplementary files

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2. Fig. 1. Diffraction pattern of the UPTFE + ZnS composite; UPTFE: 2θ = 18.08 (crystalline phase), 2θ = 32, 37, 42 (X-ray amorphous phase); ZnS: 2θ = 28.64, 47.58, 56.35 (for wurtzite dhkl = 3.15, 1.90, 1.63).

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3. Fig. 2. SEM micrographs of the original PP fiber (a) and fiber modified with UPTFE + ZnS composite (b).

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4. Fig. 3. TEM micrograph with a general view of crushed and ultrasonically dispersed PP threads modified with UPTFE + ZnS composite. The inset shows the distribution of nanoparticles by size.

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5. Fig. 4. DSC thermograms for samples of fibers based on polypropylene grade “Balen” 01030 (the compositions of the samples are given in Table 1): 1 – sample No. 1 (solid line), 2 – sample No. 2 with applied coating (dots), 3 – sample No. 3 with applied coating, treated with ultrasound (dashed line), 4 – volumetrically modified sample No. 4 (gray dashed-dotted line).

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