1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

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Abstract

The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy)[SbI4] (I) and (3-Br-1-MePy)[SbI4] (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.

About the authors

I. A. Shentseva

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia

A. N. Usol’tsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia

N. A. Korobeinikov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: korobeynikov@niic.nsc.ru
Novosibirsk, Russia; Novosibirsk, Russia

S. A. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia; Irkutsk, Russia

References

  1. Sharutin V.V., Egorova I.V., Klepikov N.N. et al. // Russ. J. Inorg. Chem. 2009. V. 54. № 11. P. 1768. https://doi.org/10.1134/S0036023609110126
  2. Buikin P.A., Rudenko A.Y., Ilyukhin A.B. et al. // Russ. J. Coord. Chem. 2020. V. 46. № 2. P. 111. https://doi.org/10.1134/S1070328420020049
  3. Buikin P.A., Rudenko A.Y., Baranchikov A.E. et al. // Russ. J. Coord. Chem. 2018. V. 44. № 6. P. 373. https://doi.org/10.1134/S1070328418060015
  4. Chen Y., Yang Z., Guo C.X. et al. // Eur. J. Inorg. Chem. 2010. № 33. P. 5326. https://doi.org/10.1002/ejic.201000755
  5. Möbs J., Gerhard M., Heine J. // Dalton Trans. 2020. V. 49. № 41. P. 14397. https://doi.org/10.1039/d0dt03427d
  6. Hrizi C., Trigui A., Abid Y. et al. // J. Solid State Chem. 2011. V. 184. № 12. P. 3336. https://doi.org/10.1016/j.jssc.2011.10.004
  7. Sharutin V.V., Pakusina A.P., Sharutina O.K. et al. // Russ. J. Coord. Chem. 2004. V. 30. № 8. P. 541. https://doi.org/10.1023/B:RUCO.0000037432.61330.07
  8. Möbs J., Stuhrmann G., Weigend F. et al. // Chem. Eur. J. 2022. https://doi.org/10.1002/chem.202202931
  9. Zhao J.-Q., Shi H.-S., Zeng L.-R. et al. // Chem. Eng. J. 2022. V. 431. https://doi.org/10.1016/j.cej.2021.134336
  10. Feng L.-J., Zhao Y.-Y., Song R.-Y. et al. // Inorg. Chem. Commun. 2022. V. 136. https://doi.org/10.1016/j.inoche.2021.109146
  11. Fateev S.A., Petrov A.A., Khrustalev V.N. et al. // Chem. Mater. 2018. V. 30. № 15. P. 5237. https://doi.org/10.1021/acs.chemmater.8b01906
  12. Petrov A.A., Marchenko E.I., Fateev S.A. et al. // Mendeleev Commun. 2022. V. 32. № 3. P. 311. https://doi.org/10.1016/j.mencom.2022.05.006
  13. Fateev S.A., Stepanov N.M., Petrov A.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 7. P. 992. https://doi.org/10.1134/S0036023622070075
  14. Fateev S.A., Khrustalev V.N., Simonova A.V. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 7. P. 997. https://doi.org/10.1134/S0036023622070087
  15. Zhang Q., Wu Y., Fu H. et al. // J. Colloid Interface Sci. 2024. V. 664. № March. P. 809. https://doi.org/10.1016/j.jcis.2024.03.057
  16. Huang Y., Yu J., Wu Z. et al. // RSC Adv. 2024. V. 14. № 7. P. 4946. https://doi.org/10.1039/d3ra07998h
  17. Chen Z., Hu Y., Wang J. et al. // Chem. Mater. 2020. V. 32. № 4. P. 1517. https://doi.org/10.1021/acs.chemmater.9b04582
  18. Dai Y., Poidevin C., Ochoa-Hernández C. et al. // Angew. Chem. Int. Ed. 2020. V. 59. № 14. P. 5788. https://doi.org/10.1002/anie.201915034
  19. Wu L.Y., Mu Y.F., Guo X.X. et al. // Angew. Chem. Int. Ed. 2019. V. 58. № 28. P. 9491. https://doi.org/10.1002/anie.201904537
  20. Lin K., Xing J., Quan L.N. et al. // Nature. 2018. V. 562. № 7726. P. 245. https://doi.org/10.1038/s41586-018-0575-3
  21. Igbari F., Wang Z.K., Liao L.S. // Adv. Energy Mater. 2019. V. 9. № 12. P. 1. https://doi.org/10.1002/aenm.201803150
  22. Stranks S.D., Snaith H.J. // Nat. Nanotechnol. 2015. V. 10. № 5. P. 391. https://doi.org/10.1038/nnano.2015.90
  23. Li X., Shi J., Chen J. et al. // Materials (Basel). 2023. V. 16. № 12. https://doi.org/10.3390/ma16124490
  24. Lei Y., Wang S., Xing J. et al. // Inorg. Chem. 2020. V. 59. № 7. P. 4349. https://doi.org/10.1021/acs.inorgchem.9b03277
  25. Kojima A., Teshima K., Shirai Y. et al. // J. Am. Chem. Soc. 2009. V. 131. № 17. P. 6050. https://doi.org/10.1021/ja809598r
  26. Green M.A., Dunlop E.D., Hohl-Ebinger J. et al. // Prog. Photovoltaics Res. Appl. 2022. V. 30. № 7. P. 687. https://doi.org/10.1002/pip.3595
  27. Hu Y.Q., Hui H.Y., Lin W.Q. et al. // Inorg. Chem. 2019. V. 58. № 24. P. 16346. https://doi.org/10.1021/acs.inorgchem.9b01439
  28. Dennington A.J., Weller M.T. // Dalton Trans. 2018. V. 47. № 10. P. 3469. https://doi.org/10.1039/c7dt04280a
  29. Mastryukov M.V., Son A.G., Tekshina E.V. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 10. P. 1652. https://doi.org/10.1134/S0036023622100540
  30. Liu H., Zhang Z., Zuo W. et al. // Adv. Energy Mater. 2023. V. 13. № 3. https://doi.org/10.1002/aenm.202202209
  31. Pai N., Chatti M., Fürer S.O. et al. // Adv. Energy Mater. 2022. V. 12. № 32. P. 2201482. https://doi.org/10.1002/aenm.202201482
  32. Adonin S.A., Sokolov M.N., Fedin V.P. // Coord. Chem. Rev. 2016. V. 312. P. 1. https://doi.org/10.1016/J.CCR.2015.10.010
  33. Wu L.-M., Wu X.-T., Chen L. // Coord. Chem. Rev. 2009. V. 253. № 23–24. P. 2787. https://doi.org/10.1016/J.CCR.2009.08.003
  34. Desiraju G.R., Shing Ho P., Kloo L. et al. // Pure Appl. Chem. 2013. V. 85. № 8. P. 1711. https://doi.org/10.1351/PAC-REC-12-05-10
  35. Suslonov V.V., Soldatova N.S., Ivanov D.M. et al. // Cryst. Growth Des. 2021. V. 21. № 9. P. 5360. https://doi.org/10.1021/acs.cgd.1c00654
  36. Eliseeva A.A., Ivanov D.M., Rozhkov A.V. et al. // JACS Au. 2021. V. 1. № 3. P. 354. https://doi.org/10.1021/jacsau.1c00012
  37. Bokach N.A., Suslonov V.V., Eliseeva A.A. et al. // CrystEngComm. 2020. V. 22. № 24. P. 4180. https://doi.org/10.1039/c6ra90077a
  38. Soldatova N.S., Postnikov P.S., Suslonov V.V. et al. // Org. Chem. Front. 2020. V. 7. № 16. P. 2230. https://doi.org/10.1039/d0qo00678e
  39. Kubasov A.S., Avdeeva V.V. // 2024. № Ii. P. 12.
  40. Ball M.L., Milić J.V., Loo Y.L. // Chem. Mater. 2022. V. 34. № 6. P. 2495. https://doi.org/10.1021/acs.chemmater.1c03117
  41. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. № 1. P. 3. https://doi.org/10.1107/S2053273314026370
  42. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3. https://doi.org/10.1107/S2053229614024218
  43. Dolomanov O.V.O. V., Bourhis L.J.L.J., Gildea R.J.R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. № 2. P. 339. https://doi.org/10.1107/S0021889808042726
  44. Oswald I.W.H., Mozur E.M., Moseley I.P. et al. // Inorg. Chem. 2019. V. 58. № 9. P. 5818. https://doi.org/10.1021/acs.inorgchem.9b00170
  45. Mantina M., Chamberlin A.C., Valero R. et al. // J. Phys. Chem. A. 2009. V. 113. № 19. P. 5806. https://doi.org/10.1021/JP8111556
  46. Pohl S., Lotz R., Saak W. et al. // Angew. Chem. Int. Ed. English. 1989. V. 28. № 3. P. 344. https://doi.org/10.1002/anie.198903441
  47. Janczak J., Perpétuo G.J. // Acta Crystallogr. C. 2006. V. 62. № 7. P. M323. https://doi.org/10.1107/S010827010601910X
  48. Li Y., Xu Z., Liu X. et al. // Inorg. Chem. 2019. V. 58. № 9. P. 6544. https://doi.org/10.1021/acs.inorgchem.9b00718
  49. Sharutin V.V., Senchurin V.S., Sharutina O.K. et al. // Russ. J. Inorg. Chem. 2011. V. 56. № 10. P. 1561. https://doi.org/10.1134/S0036023611100196
  50. Möbs J., Stuhrmann G., Wippermann S. et al. // ChemPlusChem. 2023. V. 88. № 6. P. E202200403.
  51. Cavallo G., Metrangolo P., Milani R. et al. // Chem. Rev. 2016. V. 116. № 4. P. 2478. https://doi.org/10.1021/acs.chemrev.5b00484
  52. Bhattacharyya D., Chaudhuri S., Pal A. // Vacuum. 1992. V. 43. № 4. P. 313. https://doi.org/10.1016/0042-207X(92)90163-Q
  53. Mousdis G.A., Ganotopoulos N.M., Barkaoui H. et al. // Eur. J. Inorg. Chem. 2017. V. 2017. № 28. P. 3401. https://doi.org/10.1002/ejic.201700277

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