Nickel(II) Complex with the Bis(phenolate) Pincer N-Heterocyclic Carbene Ligand: Synthesis, Structure, and Properties

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Resumo

The nickel(II) complex Ni(L)Py (I) (L is 1,3-bis(3,5-di-tert-butyl-2-phenolato)-5,5-dimethyl-(4,6-dihydropyrimidin-2-ylidene)) containing the dianionic bonded N-heterocyclic carbene (NHC) bis(phenolate) ligand is synthesized. In the presence of a stronger base (4-dimethylaminopyridine (DMAP)), the exchange reaction occurs with the replacement of pyridine in complex I by the DMAP molecule to form complex Ni(L)(DMAP) (II), the crystal structure of which is determined by XRD. The synthesized compounds are characterized by elemental analysis, mass spectrometry, and NMR spectroscopy. The spectral characteristics of the compounds are studied.

Sobre autores

Z. Gafurov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences

Email: gafurov.zufar@iopc.ru
Kazan, Russia

I. Mikhailov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences

Kazan, Russia

A. Kagilev

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences; Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University

Kazan, Russia; Kazan, Russia

I. Sakhapov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences

Kazan, Russia

A. Kantyukov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences; Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University

Kazan, Russia; Kazan, Russia

E. Zueva

Kazan National Research Technological University

Kazan, Russia

A. Dobrynin

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences

Kazan, Russia

A. Trifonov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Moscow, Russia

D. Yakhvarov

Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University

Email: yakhvar@iopc.ru
Kazan, Russia

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