Structural modifications of the platinum(II) isocyanide complexes changing their solid-state luminescence

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

Cyclometallated platinum(II) complexes with the general formula [Pt(Рpy)(CNR)2]X (HРpy = 2-phenylpyridine; R = iPr, tBu, Cy; X = BF4, OTf, PF6) containing various alkylisocyanide ligands and counterions are synthesized. The compounds are studied by elemental analysis, ESI HRMS, IR spectroscopy, and 1H, 13C{1H}, and 195Pt{1H} NMR spectroscopy. The structures of [Pt(Рpy)(CNiPr)2]BF4 and [Pt(Рpy)(CNtBu)2]BF4 are determined by XRD (CIF files CCDC nos. 2325595 and 2325527, respectively). The photophysical properties in the solution and in the solid state of the synthesized compounds are studied.

全文:

受限制的访问

作者简介

E. Antonova

St. Petersburg State University

Email: m.kinzhalov@spbu.ru
俄罗斯联邦, St. Petersburg

M. Sandzhieva

St. Petersburg National Research University of Information Technologies, Mechanics, and Optics

Email: m.kinzhalov@spbu.ru
俄罗斯联邦, St. Petersburg

M. Kinzhalov

St. Petersburg State University

编辑信件的主要联系方式.
Email: m.kinzhalov@spbu.ru
俄罗斯联邦, St. Petersburg

参考

  1. Li X., Xie Y., Li Z. // Chem Asian J. 2021. V. 16. № 19. P. 2817. https://doi.org/10.1002/asia.202100784
  2. Lee S., Han W.-S. // Inorg. Chem. Front. 2020. V. 7. № 12. P. 2396. https://doi.org/10.1039/D0QI00001A
  3. Zhang Q.-C., Xiao H., Zhang X. et al. // Chem. Soc. Rev. 2019. V. 378. № . P. 121. https://doi.org/10.1016/j.ccr.2018.01.017
  4. Katkova S.A., Kozina D.O., Kisel K.S. et al. // Dalton Trans. 2023. V. 52. № 14. P. 4595. https://doi.org/10.1039/d3dt00080j.
  5. Zhou X., Lee S., Xu Z. et al. // Chem. Rev. 2015. V. 115. № 15. P. 7944. https://doi.org/10.1021/cr500567r
  6. Eremina A.A., Kinzhalov M.A., Katlenok E.A. et al. // Inorg. Chem. 2020. V. 59. № 4. P. 2209. https://doi.org/10.1021/acs.inorgchem.9b02833
  7. Chan A.Y., Perry I.B., Bissonnette N.B. et al. // Chem. Rev. 2021. V. № . P. https://doi.org/10.1021/acs.chemrev.1c00383
  8. Li K., Chen Y., Wang J. et al. // Coord. Chem. Rev. 2021. V. 433. № . P. 213755. https://doi.org/10.1016/j.ccr.2020.213755
  9. To W.P., Wan Q.Y., Tong G.S.M. et al. // Trends Chem. 2020. V. 2. № 9. P. 796. https://doi.org/10.1016/j.trechm.2020.06.004
  10. Kinzhalov M.A., Grachova E.V., Luzyanin K.V. // Inorg. Chem. Front. 2022. V. 9. № . P. 417. https://doi.org/10.1039/D1QI01288F
  11. Lu B., Liu S., Yan D. // Chin. Chem. Lett. 2019. V. 30. № 11. P. 1908. https://doi.org/10.1016/j.cclet.2019.09.012
  12. Wang W., Zhang Y., Jin W.J. // Coord. Chem. Rev. 2020. V. 404. № . P. https://doi.org/10.1016/j.ccr.2019.213107
  13. Koshevoy I.O., Krause M., Klein A. // Coord. Chem. Rev. 2020. V. 405. № . P. https://doi.org/10.1016/j.ccr.2019.213094
  14. Yoshida M., Kato M. // Coord. Chem. Rev. 2018. V. 355. № . P. 101. https://doi.org/10.1016/j.ccr.2017.07.016
  15. Puttock E.V., Walden M.T., Williams J.A.G. // Coord. Chem. Rev. 2018. V. 367. № . P. 127. https://doi.org/10.1016/j.ccr.2018.04.003
  16. Ravotto L., Ceroni P. // Coord. Chem. Rev. 2017. V. 346. № . P. 62. https://doi.org/10.1016/j.ccr.2017.01.006
  17. Solomatina A.I., Galenko E.E., Kozina D.O. et al. // Chemistry. 2022. V. 28. № 64. P. e202202207. https://doi.org/10.1002/chem.202202207
  18. Sokolova E.V., Kinzhalov M.A., Smirnov A.S. et al. // ACS Omega. 2022. V. 7. № 38. P. 34454. https://doi.org/10.1021/acsomega.2c04110
  19. Saito D., Ogawa T., Yoshida M. et al. // Angew. Chem. Int. Ed. Engl. 2020. V. 59. № 42. P. 18723. https://doi.org/10.1002/anie.202008383
  20. Yoshida M., Kato M. // Coord. Chem. Rev. 2020. V. 408. № . P. https://doi.org/10.1016/j.ccr.2020.213194
  21. Chaaban M., Lee S., Vellore Winfred J.S.R. et al. // Small Struct. 2022. V. 3. № 9. P. 2200043. https://doi.org/10.1002/sstr.202200043
  22. Ogawa T., Sameera W.M.C., Saito D. et al. // Inorg. Chem. 2018. V. 57. № 22. P. 14086. https://doi.org/10.1021/acs.inorgchem.8b01654.
  23. Law A.S., Lee L.C., Lo K.K. et al. // J. Am. Chem.Soc. 2021. V. 143. № 14. P. 5396. https://doi.org/10.1021/jacs.0c13327
  24. Po C., Tam A.Y., Wong K.M. et al. // J. Am. Chem. Soc. 2011. V. 133. № 31. P. 12136. https://doi.org/10.1021/ja203920w
  25. Cave G.W.V., Fanizzi F.P., Deeth R.J. et al. // Organometallics. 2000. V. 19. № 7. P. 1355. https://doi.org/10.1021/om9910423
  26. Liu J., Leung C.H., Chow A.L. et al. // Chem Commun. 2011. V. 47. № 2. P. 719. https://doi.org/10.1039/c0cc03641b
  27. Dobrynin M.V., Sokolova E.V., Kinzhalov M.A. et al. // ACS Appl. Polym. Mater. 2021. V. 3. № 2. P. 857. https://doi.org/10.1021/acsapm.0c01190
  28. Hubschle C.B., Sheldrick G.M., Dittrich B. // J. Appl. Crystallogr. 2011. V. 44. № 6. P. 1281. https://doi.org/10.1107/S0021889811043202
  29. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. № 2. P. 339.
  30. CrysAlisPro. Yarnton (Oxfordshire, England): Agilent Technologies Ltd., 2012.
  31. CrysAlisPro. Yarnton (Oxfordshire, England): Agilent Technologies Ltd., 2014.
  32. CrysAlisPro. Yarnton (Oxfordshire, England): Oxford Diffraction Ltd., 2009.
  33. Katkova S.A., Sokolova E.V., Kinzhalov M.A. // Russ. J. Gen. Chem.. 2023. V. 93. № 1. P. 43. https://doi.org/10.1134/S1070363223010073
  34. Forniés J., Fuertes S., Larraz C. et al. // Organometallics. 2012. V. 31. № 7. P. 2729. https://doi.org/10.1021/om201036z
  35. Kinzhalov M.A., Boyarskii V.P. // Russ. J. Gen. Chem. 2015. V. 85. № 10. P. 2313. https://doi.org/10.1134/s1070363215100175
  36. Pawlak T., Niedzielska D., Vícha J. et al. // J. Organometal. Chem. 2014. V. 759. № . P. 58. https://doi.org/10.1016/j.jorganchem.2014.02.016
  37. Katkova S.A., Mikherdov A.S., Sokolova E.V. et al. // J. Mol. Struct. 2022. V. 1253. № . P. 132230. https://doi.org/10.1016/j.molstruc.2021.132230
  38. Katkova S.A., Eliseev I.I., Mikherdov A.S. et al. // Russ. J. Gen. Chem. 2021. V. 91. № 3. P. 393. https://doi.org/10.1134/S1070363221030099
  39. Martínez-Junquera M., Lara R., Lalinde E. et al. // J. Mater. Chem. C. 2020. V. 8. № 21. P. 7221. https://doi.org/10.1039/D0TC01163K
  40. Martinez-Junquera M., Lalinde E., Moreno M.T. // Inorg. Chem. 2022. V. 61. № 28. P. 10898. https://doi.org/10.1021/acs.inorgchem.2c01400
  41. Shahsavari H.R., Babadi Aghakhanpour R., Hossein-Abadi M. et al. // New J. Chem. 2017. V. 41. № 24. P. 15347. https://doi.org/10.1039/c7nj03110f
  42. Bondi A. // J. Phys. Chem. 1964. V. 68. № 3. P. 441. https://doi.org/10.1021/j100785a001.
  43. Katkova S.A., Luzyanin K.V., Novikov A.S. et al. // New J. Chem. 2021. V. 45. № 6. P. 2948 https://doi.org/10.1039/D0NJ05457G.
  44. Martinez-Junquera M., Lalinde E., Moreno M.T. et al. // Dalton Trans. 2021. V. 50. № 13. P. 4539. https://doi.org/10.1039/d1dt00480h

补充文件

附件文件
动作
1. JATS XML
下载
2. Scheme 1: Synthesis of isocyanide complexes I-VIII.

下载 (120KB)
索引源数据
3. Fig. 1. Structures of the organometallic cation of complexes I (a) and III (b) according to PCA data.

下载 (192KB)
索引源数据
4. Fig. 2. Non-covalent interactions between organometallic cations in complexes I (a) and III (b).

下载 (136KB)
索引源数据
5. Fig. 3. Normalized luminescence spectra of powders I-VIII at 298 K.

下载 (83KB)
索引源数据

版权所有 © Российская академия наук, 2024