Synthesis and structures of mixed-ligand lead(II) complexes with decahydro-closo-decaborate anion and azheterocyclic ligands

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Abstract

Lead(II) complexation reactions were studied in the presence of salts of the closo-decaborate anion [B10H10]2– and azaheterocyclic ligands 2,2΄-bipyridyl (bipy) or 1,10-phenanthroline (phen) in water and organic solvents (acetonitrile, DMF). Binuclear complex Pb(bipy)2[B10H10] and polymer complex [Pb(phen)[B10H10]] were isolated. The effect of solvents and reagent ratios on the composition and structures of the final complexes was studied. The complex compounds were identified by elemental analysis, IR spectroscopy, and X-ray powder diffraction. The structure of complex [Pb(bipy)2[B10H10]]2 ⋅ 2CH3CN (CCDC no. 2325841) was determined by single-crystal X-ray diffraction.

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About the authors

V. V. Avdeeva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow

A. S. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow

I. V. Kozerozhets

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow

S. E. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow

E. A. Malinina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow

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Supplementary files

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2. Scheme 1: Synthesis of the compounds discussed in this work.

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3. Fig. 1. Structure of complex I - CH3CN: structure fragment (a), packing fragment (b).

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4. Fig. 2. dnorm-Hirschfeld surface of the [B10H10]2- anion in the structure of I (a); 2D-section of the Hirschfeld surface of the anion (b) and the contact boundaries of H...H (c), H...Pb (d) and H...N (e).

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5. Fig. 3. Theoretical X-ray diffraction of the complex [Pb(Bipy)[B10H10]] [26] (blue) and practical X-ray diagram of complex II (red).

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