Optimization of the synthesis of salts [V10O28]6– for the preparation of [VO2(DMSO)4](CF3SO3) and its immobilization on polyethylene terephthalate for catalytic applications

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Abstract

Aspects of the synthesis and isolation of (Bu4N)3[H3V10O28] (I) and Na6[V10O28] · 18H2O (II) from one reaction mixture are considered. The procedure for the synthesis of compound I is optimized. The reaction of compound I and HSO3CF3 in dimethyl sulfoxide (DMSO) affords complex [VO2(DMSO)4](CF3SO3) (III). A possibility of using complex III for the preparation of catalytically active materials based on polyethylene terephthalate (PET) is shown.

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About the authors

P. A. Abramov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk

N. B. Kompan’kov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk

V. S. Sulyaeva

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk

M. N. Sokolov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk

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Supplementary files

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2. Fig. 1. Comparison of experimental XRD data (298 K) and calculated data obtained from PCA data (150 K) for complex I.

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3. Fig. 2. Comparison of experimental XRD data (298 K) and calculated data obtained from PCA data (150 K) for complex III.

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4. Fig. 3. Structure of the [V10O28]6- anion (a) and the [VO2(DMSO)4]+ cation (b). Spherical rod models, the hydrogen atoms of the methyl groups are not shown for clarity.

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5. Fig. 4. 51V NMR spectra of solutions of III (298 K) in (CD3)2SO (a), (CD3)2CO (b), D2O (c). Spectrum of complex I in CD3CN (d).

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6. Fig. 5. SEM image of the sample (a), EDX mapping of vanadium, oxygen and carbon and their joint image (b) and energy dispersive spectrum (c).

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