Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure

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Abstract

The multicomponent chemical reactions of Fe(SO4)∙7H2O, Li(Рiv), K(Рiv) (Рiv is pivalate anion), and heterocyclic N-donor ligands (pyridine (Рy), 1,10-phenanthroline (Рhen)) in anhydrous acetonitrile under an inert atmosphere afford new heterometallic tetranuclear complexes [FeII2
Li2(Рiv)6(Рy)4] (I) and [FeII2
Li2(Рiv)6(Рhen)2] (II) in which all carboxylate anions act as bridging ligands. The molecular and crystal structures of the compounds are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2220576 (I) and 2220577 (II·2CH3CN). In the studied complexes, the iron(II) atoms exist in the distorted octahedral ligand environment.

About the authors

D. S. Yambulatov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sanikol@igic.ras.ru
Россия, Москва

Yu. K. Voronina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sanikol@igic.ras.ru
Россия, Москва

S. A. Nikolaevskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sanikol@igic.ras.ru
Россия, Москва

A. I. Poddel’skii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sanikol@igic.ras.ru
Россия, Москва

M. A. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sanikol@igic.ras.ru
Россия, Москва

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Author for correspondence.
Email: sanikol@igic.ras.ru
Россия, Москва

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Copyright (c) 2023 Д.С. Ямбулатов, Ю.К. Воронина, С.А. Николаевский, А.И. Поддельский, М.А. Кискин, И.Л. Еременко