Гидрирование продуктов переработки полисахаридов биомассы, содержащих фурановый фрагмент, на палладиевом катализаторе на основе мезопористого алюмосиликата

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Синтезирован катализатор на основе мезопористого алюмосиликата Al-MCM-41, содержащий наночастицы палладия. Катализатор исследован в жидкофазном гидрировании фурфурола, 5-гидроксиметилфурфурола и фурфурилового спирта при начальном давлении водорода 5 МПа. Изучено влияние времени реакции, концентрации катализатора, температуры и природы растворителя на конверсию и распределение продуктов гидрирования фурфурола. Установлено, что в водной среде в присутствии Pd/Al-MCM-41 фурфурол превращается преимущественно в тетрагидрофурфуриловый спирт в мягких условиях (100°С, 45 мин) при полной конверсии субстрата. Показано влияние структуры продуктов переработки полисахаридов биомассы, содержащих фурановый фрагмент, на конверсию и селективность процесса гидрирования на катализаторе Pd/Al-MCM-41 в водной среде.

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Sobre autores

Екатерина Ролдугина

Московский государственный университет им. М. В. Ломоносова

Autor responsável pela correspondência
Email: rolduginakate@mail.ru
ORCID ID: 0000-0002-9194-1097

химический факультет, к.х.н.

Rússia, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Анастасия Ситникова

Московский государственный университет им. М. В. Ломоносова

Email: rolduginakate@mail.ru
ORCID ID: 0009-0009-1429-3477

химический факультет

Rússia, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Максим Бороноев

Московский государственный университет им. М. В. Ломоносова

Email: rolduginakate@mail.ru
ORCID ID: 0000-0001-6129-598X

химический факультет, к.х.н.

Rússia, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Искандер Шакиров

Московский государственный университет им. М. В. Ломоносова

Email: rolduginakate@mail.ru
ORCID ID: 0000-0003-2029-693X

химический факультет, к.х.н.

Rússia, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

Юлия Кардашева

Московский государственный университет им. М. В. Ломоносова

Email: rolduginakate@mail.ru
ORCID ID: 0000-0002-6580-1082

химический факультет, к.х.н.

Rússia, 119991, ГСП-1, г. Москва, Ленинские горы, д. 1, стр. 3

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2. Fig. 1. Ammonia temperature-programmed desorption spectrum (a) and small-angle scattering diffraction pattern (b) of mesoporous aluminosilicate Al-MCM-41.

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3. Fig. 2. Nitrogen adsorption-desorption isotherms and pore size distribution of mesoporous aluminosilicate Al-MCM-41 and Pd-containing catalyst based on it.

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4. Fig. 3. X-ray diffraction pattern (a), micrograph and Pd nanoparticle size distribution diagram (b) of Pd catalyst based on mesoporous aluminosilicate Al-MCM-41.

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5. Fig. 4. Hydrogenation of furfural in the presence of Pd/Al-MCM-41 catalyst at different reaction times (a) and substrate/catalyst weight ratios (b). Reaction conditions: 0.6 mmol furfural, 2 ml water, 5 MPa H2, 100°C, 3 mg Pd/Al-MCM-41 (a), 45 min (b). Other products: 4-oxopentanal, 5-hydroxy-2-pentanone. * 100–200°C, 45 min, 3 mg Al-MCM-41 support.

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6. Fig. 5. Hydrogenation of furfural in the presence of Pd/Al-MCM-41 catalyst in aqueous medium (a) and in toluene (b). Reaction conditions: 0.6 mmol furfural, 3 mg Pd/Al-MCM-41, 5 MPa H2, 30 min, 2 ml water (a), 2 ml toluene (b). Other products: 2-methyltetrahydrofuran, 2-methylfuran, 3-hydroxycyclopentanone (a), C5+ condensation products (b). * 8 mg Pd/Al-MCM-41.

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7. Fig. 6. Hydrogenation of furfuryl alcohol (a) and 5-hydroxymethylfurfural (b) in the presence of Pd/Al-MCM-41 catalyst. Reaction conditions: 0.6 mmol substrate, 2 ml water, 5 MPa H2, 30 min, Pd/Al-MCM-41 — 3 mg (a), 6 mg (b).

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