Some features of trichlorobiphenyls photolysis

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Abstract

The photolytic decomposition of the Trikhlorbifenil mixture, 2,4,5- and 2,4,6-trichlorobiphenyls under an influence of ultraviolet radiation in presence of tungsten oxide as a catalyst in a methanol medium was studied. A higher rate of photolysis of individual congeners of polychlorbiphenyls was established compared to the congeners of the Trikhlorbifenil mixture. The influence of structural features of polychlorarenes on a depth of photodecomposition and a routes of formation of photodestruction products was considered.

About the authors

T. I. Gorbunova

I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: gorbunova@ios.uran.ru

M. G. Pervova

I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

G. S. Zakharova

Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences

N. V. Podval'naya

Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences

A. N. Enyashin

Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences

V. I. Saloutin

I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

O. N. Chupakhin

I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

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