Extraction of lanthanides(III) with of bis[N-octyl-N-(2-diphenylphosphinylethyl)]amide of diglycolic acid from nitric acid solutions

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Abstract

Extraction of microquantities of lanthanides(III) from HNO3 solutions with solutions of bis[N-octyl-N-(2-diphenylphosphinylethyl)]amide of diglycolic acid [Ph2P(O)CH2CH2N(Oct)C(O)CH2]2O in organic solvents was studied. Stoichiometry of extracted complexes was determined, influence of extractant structure, nature of organic diluent and composition of aqueous phase on efficiency and selectivity of extraction of lanthanide(III) ions into organic phase was considered. It was shown that modification of diglycolamides by introduction of additional coordinating groups CH2CH2P(O)Ph2 into their molecule via amide nitrogen atom leads to increase of extraction of lanthanides(III) from neutral and weakly acidic nitrate media when using a mixture of n-dodecane with tributylphosphate as a solvent.

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About the authors

А. N. Turanov

Yu. A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences

Email: karan@iptm.ru
ORCID iD: 0000-0002-5064-191X
Russian Federation, 142432, Chernogolovka

V. K. Karandashev

Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences

Author for correspondence.
Email: karan@iptm.ru
ORCID iD: 0000-0003-0684-272X
Russian Federation, 142432, Chernogolovka

Zh. P. Burmii

Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences

Email: karan@iptm.ru
ORCID iD: 0000-0003-4195-9392
Russian Federation, 142432, Chernogolovka

K. V. Tcarkova

National Research Centre “Kurchatov Institute”

Email: karan@iptm.ru
ORCID iD: 0000-0001-8730-0521
Russian Federation, 123182, Moscow

O. I. Artyushin

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: karan@iptm.ru
ORCID iD: 0000-0001-6333-5973
Russian Federation, 119991, Moscow

N. A. Bondarenko

National Research Centre “Kurchatov Institute”

Email: karan@iptm.ru
ORCID iD: 0000-0002-6704-6957
Russian Federation, 123182, Moscow

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Supplementary files

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2. Scheme 1.

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3. Fig. 1. Distribution coefficients of Ln(III) during extraction with 0.01 mol/L solutions of diamide 1 in n-dodecane containing 30% TBP (1), octanol (2), nitrobenzene (3), dichloroethane (4), and chloroform (5) from 3 mol/L HNO3 solutions.

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4. Fig. 2. Dependence of the distribution coefficients of Ln(III) on the concentration of HNO3 in the aqueous phase during extraction with 0.01 mol/l solutions of diamide 1 in n-dodecane containing 30% TBP.

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5. Fig. 3. Dependence of the distribution coefficients of Ln(III) on the concentration of HNO3 in the aqueous phase during extraction with solutions of 0.01 mol/l TODGA in n-dodecane containing 30% TBP.

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6. Fig. 4. Distribution coefficients of Ln(III) during extraction with 0.01 mol/L solutions of diamide 1 (1, 4–6) and TODGA (2, 3, 7, 8) in n-dodecane containing 30% TBP from solutions of 3 mol/L NH4NO3 (1, 8), 1 mol/L HNO3 (5, 7), 3 mol/L HNO3 (3, 6), and 5 mol/L HNO3 (2, 4).

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7. Fig. 5. Dependence of the distribution coefficients of Ln(III) on the concentration of diamide 1 in n-dodecane containing 30% TBP, during extraction from a 3 mol/l HNO3 solution.

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