Synthesis and some properties of magnesium, zinc, and erbium tetra-3(4)-methylphenyldiazenylphtalocyanines

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Abstract

The peripherally and non-peripherally substituted Zn(II), Mg(II), and Er(III) phthalocyanine complexes were obtained from 3(4)-(4-methylphenyldiazenylphenoxy)phthalonitrile. The effect of the complexing metal and the location of the substituent on the spectral properties of the obtained compounds was shown. The acid-base properties of non-peripherally substituted metal phthalocyanines were studied. The quantum yield and fluorescence lifetime for the synthesized metal complexes were determined.

About the authors

A. N. Bychkova

Ivanovo State University of Chemistry and Technology

T. V. Tikhomirova

Ivanovo State University of Chemistry and Technology

Email: tararjkina@mail.ru

K. Yu. Kazaryan

Ivanovo State University of Chemistry and Technology

E. A. Mykina

Ivanovo State University of Chemistry and Technology

A. S. Vashurin

Ivanovo State University of Chemistry and Technology

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