Mn(II)-cu(I) hybrid complex based on 1,3,5-tris(diphenylphosphinyl)benzene

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Abstract

The reaction of 1,3,5-tris(diphenylphosphinyl)benzene (L) with MnI2 in the presence of CuI (wet MeCN, 25°C, 30 min) leads to the formation of a complex [MnL4(H2O)2][Cu5I7(CH3CN)]·7MeCN with yield of 72%. The Mn2+ ion of this complex has a distorted Mn@O6 octahedral environment formed by four L ligands and two coordinated water molecules. The [Cu5I7(CH3CN)]2- anion has an unprecedented structure of the {Cu5I7} backbone, which includes five copper atoms bound by bridging iodide ions (µ2, µ3, µ4), as well as four short Cu···Cu contacts (<2.80 Å). It is shown that the synthesized complex at 298 K exhibits weak photoluminescence attributed to cluster-centered phosphorescence from the iodocuprate anion.

About the authors

M. P Davydova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

I. Yu. Bagryanskaya

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences

E. Kh. Sadykov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

V. K Brel

A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: v_brel@mail.ru

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