Supramolecular Hybrid Complexes Based on Octahedral Molybdenum(II) Iodide Cluster and Zinc(II) Porphyrin

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The possibility of the formation of supramolecular hybrids based on two photosensitizers, an octahedral molybdenum(II) iodide cluster with six terminal isonicotinate ligands (Bu4N)2[{Mo6I8}(OOC–C5H4N)6] (PyMoC, C) and A4-type zinc(II) porphyrin (ZnTPP, P), has been demonstrated. Spectrophotometric and NMR titration methods have shown that the formation of CPn complexes (n = 1–6) occurs in solutions of noncoordinating chlorinated solvents due to the formation of metal–N-ligand coordination bonds between the components. The use of an octahedral cluster as a hexatopic N-ligand and the lability of the Zn···NPy bonds together lead to the formation of a series of CPn complexes (n = 1–6), which are in dynamic equilibrium in solution. Nevertheless, conditions have been selected to isolate single crystals of individual forms CP4 + 2 and CP6 + 2, and their structures have been determined by X-ray diffraction analysis. The PyMoC cluster turns out to coordinate four or six ZnTPP molecules, respectively, while both structures contain two “extramolecules” of zinc(II) porphyrin bound to the cluster via hydrogen bonds involving the oxygen atoms of the isonicotinate groups and protons of water axially coordinated to the porphyrin metal center.

Авторлар туралы

M. Volostnykh

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: marinavolostnykh@gmail.com
119071, Moscow, Russia

P. Loboda

Department of Fundamental Physical and Chemical Engineering, Moscow State University

Email: marinavolostnykh@gmail.com
119234, Moscow, Russia

A. Sinelshchikova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: marinavolostnykh@gmail.com
119071, Moscow, Russia

P. Dorovatovskii

National Research Centre Kurchatov Institute

Email: marinavolostnykh@gmail.com
123182, Moscow, Russia

G. Kirakosyan

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: marinavolostnykh@gmail.com
119071, Moscow, Russia; 119991, Moscow, Russia

M. Mikhaylov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: marinavolostnykh@gmail.com
630090, Novosibirsk, Russia

M. Sokolov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: marinavolostnykh@gmail.com
630090, Novosibirsk, Russia

Yu. Gorbunova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Department of Fundamental Physical and Chemical Engineering, Moscow State University; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: marinavolostnykh@gmail.com
119071, Moscow, Russia; 119234, Moscow, Russia; 119991, Moscow, Russia

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© М.В. Волостных, П.А. Лобода, А.А. Синельщикова, П.В. Дороватовский, Г.А. Киракосян, М.А. Михайлов, М.Н. Соколов, Ю.Г. Горбунова, 2023