Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

I. A. Karavaev; Караваев И. А.; E. V. Savinkina; Савинкина Е. В.; S. S. Ponkrashina; Понкрашина С. С.; M. S. Grigor’ev; Григорьев М. С.

doi:10.31857/S0044457X22601948

Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

Authors: Karavaev I.A.¹, Savinkina E.V.¹, Ponkrashina S.S.¹, Grigor’ev M.S.²
Affiliations:
1. Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University
2. Frumkin Institute of Physical Chemistry and Electrochemistry
Issue: Vol 68, No 7 (2023)
Pages: 923-929
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjeid.com/0044-457X/article/view/665225
DOI: https://doi.org/10.31857/S0044457X22601948
EDN: https://elibrary.ru/RHLQQD
ID: 665225

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Abstract
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Abstract

Coordination compounds [Zn(H2O)4(Ur)2](NO3)2, [M(H2O)2(Ur)2(NO3)3] (M = Ce, Nd), and [Dy(H2O)(Ur)2(NO3)3] have been synthesized by the reaction of nitrates of zinc or rare earth elements with urea (Ur) in an aqueous solution. Their composition has been determined and structural features have been established using elemental analysis, IR spectroscopy, and X-ray diffraction analysis. For the zinc complex, a polymorphic transition has been found at 181 K.

Keywords

nitrates of rare earth elements, urea, X-ray diffraction analysis, polymorphism

About the authors

I. A. Karavaev

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

E. V. Savinkina

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

S. S. Ponkrashina

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

M. S. Grigor’ev

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: savinkina@mirea.ru
119071, Moscow, Russia

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