New Method for Synthesis of Substituted 1-Amidine-closo-decaborates [1-B10H9NH=C(R1)NHR2] (R1 = Me, iPr, Ph; R2 = nBu, Bn)

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Abstract

The process of nucleophilic substitution of the phenyliodonium substituent in the [1-B10H9IPh]– anion with primary amines in organic nitriles has been studied. It has been shown that the reaction proceeds with the formation of a mixture of products, namely, 1-monoalkylammonio-closo-decaborate and the corresponding amidine, which is formed when an amine molecule is added to the nitrile. The resulting products have been characterized by 1H, 11B, 13C NMR spectroscopies, IR absorption spectroscopy, and high-resolution ESI mass spectroscopy.

About the authors

A. A. Bil’bulyan

Mendeleev University of Chemical Technology of Russia

Email: zhdanov@igic.ras.ru
125047, Moscow, Russia

A. V. Nelyubin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

N. A. Selivanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

A. Yu. Bykov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

I. N. Klyukin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

A. P. Zhdanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

K. Yu. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

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Copyright (c) 2023 А.А. Бильбулян, А.В. Нелюбин, Н.А. Селиванов, А.Ю. Быков, И.Н. Клюкин, А.П. Жданов, К.Ю. Жижин, Н.Т. Кузнецов