Development of a new combined approach to the synthesis of a cathode material based on a solid solution of the composition Li2CoMn3O8

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Abstract

Cathode materials based on solid solutions of the composition Li2CoMn3O8 were obtained by a combined method and their characteristics were studied. It was found that Li2CoMn3O8 has high electrochemical properties, which makes it a promising cathode material for lithium-ion batteries, an alternative to LiCoO2. Using X-ray phase analysis and spectrometry, the resulting phases were identified and their chemical composition was determined. Electron microscopy and Brunauer–Emmett–Teller methods were used to study the structure and morphology. A technological scheme for the production of Li2CoMn3O8 has been proposed, which ensures the formation of nano-sized samples with a high specific surface area and improved electrochemical characteristics. The electrochemical properties of the synthesized samples were studied.

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About the authors

R. I. Korneykov

Sakhalin State University; Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
Russian Federation, Yuzhno-Sakhalinsk; Apatity

V. V. Efremov

Sakhalin State University; Institute of North Industrial Ecology Problems Separate subdivision of the Federal State Budgetary Institution of Science of the Federal Research Center “Kola Science Center”

Author for correspondence.
Email: v.efremov@ksc.ru
Russian Federation, Yuzhno-Sakhalinsk; Apatity

S. V. Aksenova

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
Russian Federation, Apatity

K. A. Kesarev

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
Russian Federation, Apatity

O. I. Akhmetov

Sakhalin State University

Email: v.efremov@ksc.ru
Russian Federation, Yuzhno-Sakhalinsk

O. B. Shcherbina

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
Russian Federation, Apatity

I. R. Elizarova

Institute of North Industrial Ecology Problems Separate subdivision of the Federal State Budgetary Institution of Science of the Federal Research Center “Kola Science Center”

Email: v.efremov@ksc.ru
Russian Federation, Apatity

I. G. Tananaev

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
Russian Federation, Apatity

O. O. Shichalin

Sakhalin State University

Email: v.efremov@ksc.ru
Russian Federation, Yuzhno-Sakhalinsk

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Supplementary files

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2. Rice. 1. X-ray diffraction patterns of synthesized Li2CoMn3O8 samples: a – ratio Li : Co, Mn = 2.5 : 1, τ = 2.5 h; b – Li : Co, Mn = 2.5 : 1, τ = 1.5 h; c – Li : Co, Mn = 2.23 : 1, τ = 2.5 h; d – Li : Co, Mn = 1.95 : 1, τ = 2.5 h.

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3. Fig. 2. SEM images of Li2CoMn3O8 samples at different magnifications: a – ratio Li:Co,Mn = 2.5:1; b – Li:Co,Mn = 2.23:1.

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4. Fig. 3. IR spectrum of Li2CoMn3O8 obtained at a ratio of Li:Co,Mn = 2.23:1.

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5. Fig. 4. Basic technological scheme for obtaining Li2CoMn3O8.

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6. Fig. 5. Complex impedance diagrams of Li2CoMn3O8 samples synthesized at a ratio of Li:Co,Mn = 2.5:1 (a) and 2.23:1 (b).

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7. Fig. 6. Equivalent circuit.

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