Polymeric iodobismuthates Cat{[BiI4]} with pyridinium-derived cations: structure and properties

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Abstract

Two novel bismuth(III) iodide complexes – (1,3,4-MePy){[BiI4]} (1) и (3-Br-1-MePy){[BiI4]} (2)) – were synthesized by the reaction of iodides of corresponding cations with BiI3 in organic solvents. Crystal structure of the compounds was determined by X-ray diffraction; For both complexes, the thermal stability was studied, and the optical band gap values were experimentally estimated.

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About the authors

I. A. Shentseva

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: usoltsev@niic.nsc.ru
Russian Federation, Novosibirsk, 630090

A. U. Usoltsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: usoltsev@niic.nsc.ru
Russian Federation, Novosibirsk, 630090

N. A. Korobeynikov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: usoltsev@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090

I. V. Korolkov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: usoltsev@niic.nsc.ru
Russian Federation, Novosibirsk, 630090

M. N. Sokolov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: usoltsev@niic.nsc.ru
Russian Federation, Novosibirsk, 630090

S. A. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Irkutsk Favorsky Institute of Chemistry SB RAS

Email: usoltsev@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Irkutsk, 664033

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Supplementary files

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2. Fig. 1. Crystal packing of compound 1 along the crystallographic axis a.

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3. Fig. 2. Br---I contacts (dashed line) in crystal structure 2. Hydrogen atoms are not shown.

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4. Fig. 3. Stacking interactions in the structures of compounds 1 and 2. For C---Br interactions the distances are signed.

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5. Fig. 4. Powder diffractograms of compounds 1 (a) and 2 (b): black - calculated, red - experimental.

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6. Fig. 5. TG, DTG and DTA curves for compounds 1 (a) and 2 (b).

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7. Fig. 6. Diffuse reflectance spectra of compounds 1 (a) and 2 (b).

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