Synthesis of Boron Nitride by Reduction of Boron Oxide with Aluminum in Nitrogen

D. A. Tkachev; Ткачев Д. А.; M. Kh. Ziatdinov; Зиатдинов М. Х.; I. A. Zhukov; Жуков И. А.; V. A. Litvinova; Литвинова В. А.; I. A. Belchikov; Бельчиков И. А.; N. G. Kravtsov; Кравцов Н. Г.

doi:10.31857/S0044457X23600354

Synthesis of Boron Nitride by Reduction of Boron Oxide with Aluminum in Nitrogen

Authors: Tkachev D.A.¹, Ziatdinov M.K.¹, Zhukov I.A.¹, Litvinova V.A.², Belchikov I.A.¹, Kravtsov N.G.¹
Affiliations:
1. Tomsk State University
2. Tomsk State University of Architecture and Building
Issue: Vol 68, No 10 (2023)
Pages: 1405-1412
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjeid.com/0044-457X/article/view/666176
DOI: https://doi.org/10.31857/S0044457X23600354
EDN: https://elibrary.ru/AJOUQB
ID: 666176

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The paper presents the results of studies of the self-propagating high temperature synthesis (SHS) of boron nitride via chemical reduction of boron oxide with aluminum in a nitrogen medium. The phase composition of the powder reaction products depending on the nitrogen pressure during the synthesis was studied by X-ray diffraction. It was found that SHS in the B2O3–Al system gives the BN–Al2O3 powder material containing 20–28 wt % hexagonal boron nitride depending on the nitrogen pressure. Microstructure examination showed that the obtained powder materials contains separate hexagonal BN particles with <3 μm size. The differences in the density and morphology of BN and Al2O3 determine the possibility of BN isolation from the obtained powder mixture by the pneumatic powder separation methods.

Keywords

self-propagating high-temperature synthesis, powder materials, hexagonal boron nitride, phase composition

References

Перевислов C.Н. // Новые огнеупоры. 2019. № 6. P. 35. https://doi.org/10.1007/s11148-019-00355-5
Chen B., Bi Q., Yang J. et al. // Tribol. Int. 2008. V. 41. № 12. P. 1145. https://doi.org/10.1016/j.triboint.2008.02.014
Engler M., Lesniak C., Damasch R. et al. // Ceram. Forum Int. 2007. V. 84. № 12. P. E49.
Eichler J., Lesniak C. // J. Eur. Ceram. Soc. 2008. V. 28. № 5. P. 1105. https://doi.org/10.1016/j.jeurceramsoc.2007.09.005
Sigl L.S., Hunold K. // Iron Steelmaker. 1991. V. 18. № 2. P. 31.
Rudolph S. Aluminium Cast House Technology: Seventh Australian Asian Pacific Conference. John Wiley & Sons, 2013. 163 p.
Santosh S., Rajkumar K., Gnanavelbabu A. // Mater. Sci. Forum. Trans Tech Publications. 2015. V. 830–831. P. 87. https://doi.org/10.4028/www.scientific.net/MSF.830-831.87
Jia D., Zhou L., Yang Z. et al. // J. Am. Ceram. Soc. 2011. V. 94. № 10. P. 3552. https://doi.org/10.1111/j.1551-2916.2011.04540.x
Jia K., Meng X., Wang W. // Processes. 2021. V. 9. № 5. P. 871. https://doi.org/10.3390/pr9050871
Bao J. // Electron. Mater. Lett. 2016. V. 12. P. 1. https://doi.org/10.1007/s13391-015-5308-2
Kumar R., Sahoo. S., Joanni E. et al. // Nano Res. 2019. V. 12. № 11. P. 2655. https://doi.org/10.1007/s12274-019-2467-8
Liu T., Li Y., He J. et al. // New J. Chem. Royal Soc. Chem. 2019. V. 43. № 8. P. 3280. https://doi.org/10.1039/C8NJ05299A
Chao Y., Tang B., Luo J. et al. // J. Colloid Interface Sci. 2021. V. 584. P. 154. https://doi.org/10.1016/j.jcis.2020.09.075
Zhao G., Wang A., He W. et al. // Adv. Mater. Interfaces. 2019. V. 6. № 7. P. 1900062. https://doi.org/10.1002/admi.201900062
Yoosefian M., Etminan N., Zeraati Moghani M. et al. // Superlattices Microstruct. 2016. V. 98. P. 325. https://doi.org/10.1016/j.spmi.2016.08.049
He Y., Li D., Gao W. et al. // Nanoscale. 2019. V. 11. № 45. P. 21909. https://doi.org/10.1039/C9NR07153A
Chigo-Anota E., Escobedo-Morales A., Hermandez-Cocoletzi H. et al. // Physica E: Low Dimens. Syst. Nanostruct. 2015. V. 74. P. 538. https://doi.org/10.1016/j.physe.2015.08.008
Sukhorukova I.V., Zhitnyak I.Y., Kovalskii A.M. et al. // ACS Appl. Mater. Interfaces. 2015. V. 7. № 31. P. 17217. https://doi.org/10.1021/acsami.5b04101
Hu J., Yue M., Zhang P. et al. // Angew. Chem. Int. 2020. V. 59. № 17. P. 6715. https://doi.org/10.1002/anie.201914819
Yoon S.J., Jha A. // J. Mater. Sci. 996. V. 31. № 9. P. 2265. https://doi.org/10.1007/BF00356318
Tagawa H., Itouji O. // Bull. Chem. Soc. Jpn. 962. V. 35. № 9. P. 1536. https://doi.org/10.1246/bcsj.35.1536
Hirano S.-I., Yogo T., Asada S. et al. // J. Am. Ceram. Soc. 1989. V. 72. № 1. P. 66. https://doi.org/10.1111/j.1151-2916.1989.tb05955.x
Chen G.-Q., He X.-D., Han J.-C. et al. // J. Mater. Sci. Lett. 2000. V. 19. № 1. P. 81. https://doi.org/10.1023/A:1006772320587
Haubner R., Wilhelm M., Weissengacher R. et al. Structure and Bonding. Berlin, Heidelberg: Springer Berlin Heidelberg, 2002. P. 1. https://doi.org/10.1007/3-540-45623-6_1
Gafri O., Grill A., Itzhak D. et al. // Thin Solid Films. 1980. V. 72. № 3. P. 523. https://doi.org/10.1016/0040-6090(80)90542-8
Evseev N.S., Matveev A.E., Nikitin P.Y. // Russ. J. Inorg. Chem. 2022. V. 67. № 8. P. 1319. https://doi.org/10.1134/S0036023622080095
Bazhin P.M., Konstantinov A.S., Chizhikov A.P. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 12. P. 2040. https://doi.org/10.1134/S0036023622601696
Сафаева Д.Р., Титова Ю.В., Майдан Д.А. // Современные материалы, техника и технологии. 2018. № 5(20). С. 70.
Сафаева Д.Р., Титова Ю.В., Майдан Д.А. // Современные материалы, техника и технологии. 2019. № 5(26). С. 164.
Borovinskaya I.P., Ignat′eva T.I., Vershinnikov V.I. et al. // Inorg. Mater. 2003. V. 39. P. 588. https://doi.org/10.1023/A:1024097119257
Амосов А.П., Боровинская И.П., Мержанов А.Г. Порошковая технология самораспространяющегося высокотемпературного синтеза материалов. М.: Машиностроение-1, 2007. 567 с.
Мержанов А.Г., Мукасьян А.P. // Твердопламенное горение. М.: ООО “ТОРУС ПРЕСС”, 2007. 336 с.