Microwave-Assisted Hydrothermal Synthesis of Ceric-Ammonium Phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3

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Abstract

The possibility of preparation of crystalline double cerium(IV) phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3 under the conditions of microwave-assisted hydrothermal synthesis has been analyzed. It has been shown that these phosphates in a single-phase state can be obtained in the temperature range of 130–190°С with a synthesis duration of ≥5 min, while the phase composition of the synthesis products is determined by the molar ratio of ammonia and phosphoric acid in the reaction mixture. Short-term (5 min) low-temperature (130°С) hydrothermal synthesis under microwave heating leads to the preparation of (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3 with a particle size of ~70 and ~200 nm, respectively. At higher temperatures and treatment times (190°C and 24 h), the particle size of these phases increases to ~200 and ~500 nm, respectively. For the first time, the value of the optical band gap for (NH4)2Ce(PO4)2⋅H2O was determined to be 2.8 and 3.1 eV for indirect and direct transitions, respectively.

About the authors

I. V. Tronev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

E. D. Sheichenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

L. S. Razvorotneva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

E. A. Trufanova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

P. V. Minakova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

T. O. Kozlova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: van@igic.ras.ru
119991, Moscow, Russia

A. E. Baranchikov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: van@igic.ras.ru
119991, Moscow, Russia

V. K. Ivanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Author for correspondence.
Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

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Copyright (c) 2023 И.В. Тронев, Е.Д. Шейченко, Л.С. Разворотнева, Э.А. Труфанова, П.В. Минакова, Т.О. Козлова, А.Е. Баранчиков, В.К. Иванов