Ce0.9(Mg,Ni)0.1O2: Composite or Solid Solution

M. N. Smirnova; Смирнова М. Н.; G. D. Nipan; Нипан Г. Д.; M. A. Kop’eva; Копьева М. А.; G. E. Nikiforova; Никифорова Г. Е.; G. A. Buzanov; Бузанов Г. А.; E. I. Kozhukhova; Кожухова Е. И.; I. V. Kozerozhets; Козерожец И. В.; A. D. Yapryntsev; Япрынцев А. Д.; A. A. Arkhipenko; Архипенко А. А.; M. S. Doronina; Доронина М. С.

doi:10.31857/S0044457X23600159

Ce0.9(Mg,Ni)0.1O2: Composite or Solid Solution

Authors: Smirnova M.N.¹, Nipan G.D.², Kop’eva M.A.¹, Nikiforova G.E.¹, Buzanov G.A.¹, Kozhukhova E.I.³, Kozerozhets I.V.¹, Yapryntsev A.D.¹, Arkhipenko A.A.¹, Doronina M.S.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
3. National Research Center “Kurchatov Institute,” IREA
Issue: Vol 68, No 7 (2023)
Pages: 896-903
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjeid.com/0044-457X/article/view/665222
DOI: https://doi.org/10.31857/S0044457X23600159
EDN: https://elibrary.ru/RIKAIU
ID: 665222

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Abstract
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Abstract

Samples of the composition Ce0.9(Mg1 – xNix)0.1O2 (0 ≤ x ≤ 1, step x = 0.1) have been obtained by gel combustion followed by hydrothermal treatment. X-ray powder diffraction data have showed that after gel combustion and annealing at 1100°C, composite CeO2 (fluorite structure)/solid solution Mg1 – xNixO (halite structure) is formed, and additional hydrothermal treatment followed by annealing promotes the formation of limited solid solution Ce0.9(Mg1 – xNix)0.1O2. According to the results of IR spectroscopy, the CeO2/Mg1 – xNixO composite does not adsorb CO2 even in the presence of water vapor, which is also confirmed by diffuse reflectance spectra in the UV-visible region. On the contrary, the Ce0.9(Mg1 – xNix)0.1O2 solid solution absorbs CO2, as evidenced by the results of IR spectroscopy and thermogravimetric analysis.

Keywords

cerium oxide, gel combustion method, polyvinyl alcohol, hydrothermal treatment, CO2 sorption

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