Photophysical and Photochemical Properties of Perylene–(Cyanine Dye) Dyad in the VIS–NIR Spectrum Region

A. V. Kozlov; Козлов А. В.; L. R. Sizov; Сизов Л. Р.; D. V. Revina; Ревина Д. В.; A. Yu. Rybkin; Рыбкин А. Ю.; N. S. Goryachev; Горячев Н. С.

doi:10.31857/S0044453723050138

Photophysical and Photochemical Properties of Perylene–(Cyanine Dye) Dyad in the VIS–NIR Spectrum Region

Autores: Kozlov A.V.¹, Sizov L.R.¹, Revina D.V.¹^,2, Rybkin A.Y.¹, Goryachev N.S.¹^,2
Afiliações:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
2. Moscow State University
Edição: Volume 97, Nº 5 (2023)
Páginas: 602-606
Seção: ФИЗИКА И ХИМИЯ ЭЛЕМЕНТАРНЫХ ХИМИЧЕСКИХ ПРОЦЕССОВ
##submission.dateSubmitted##: 27.02.2025
##submission.datePublished##: 01.05.2023
URL: https://rjeid.com/0044-4537/article/view/668732
DOI: https://doi.org/10.31857/S0044453723050138
EDN: https://elibrary.ru/MRDPQG
ID: 668732

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Resumo

The photophysical properties of an original covalently-bonded dyad based on a perylene derivative and IR-780 cyanine dye were studied. The dyad has pronounced absorption in the NIR region of the spectrum and a strong fluorescence signal, which is weakly quenched by the influence of the perylene derivative. Upon excitation of the dyad in the absorption region of perylene, a fluorescence signal from IR-780 is detected due to the Förster energy transfer mechanism. It is shown that the dyad does not generate singlet oxygen upon photoexcitation in the NIR region of the spectrum. However, it can generate superoxide anion radicals, indicating the presence of the photoinduced electrons transfer from the dye to the perylene.

Palavras-chave

perylene, cyanine dye, dyad, fluorescence, NIR, electron transfer

Bibliografia

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