Thermodynamic properties of multicomponent oxide systems based on CeO2 according to high-temperature mass-spectrometry data

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Abstract

Experimental data on the study of thermodynamic properties of various oxide systems containing cerium dioxide, both in the gaseous and condensed phase, are systematized. A number of regularities are revealed that allow predicting the thermochemical characteristics of these systems.

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About the authors

S. M. Shugurov

St. Petersburg State University

Author for correspondence.
Email: s.shugurov@spbu.ru

Institute of Chemistry

Russian Federation, St. Petersburg

S. I. Lopatin

Institute of Silicate Chemistry of the Russian Academy of Sciences

Email: s.shugurov@spbu.ru
Russian Federation, St. Petersburg

O. A. Zhinkina

St. Petersburg State University

Email: s.shugurov@spbu.ru

Institute of Chemistry

Russian Federation, St. Petersburg

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2. Fig. 1. Dependences of the enthalpies of atomization of gaseous cerium-containing oxygen associates on the enthalpies of formation of anion-forming oxides: 1 – CePO2, 2 — CeWO3, 3 — CeMoO4, 4 — CeWO4, 5 — CeMo2O7.

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