Fluorine-Containing Polydentate Bis(heterocycles) Based on Di- And Triketone Analogs in the Synthesis of Zinc(II) Complexes

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Abstract

An approach to the synthesis of polydentate ligands in which the NH-pyrazole cycle is connected by the hydrazone group to the azine fragment (pyridine or pyrimidine) is developed. In the reactions with zinc(II) chloride, the synthesized bis(heterocyclic) compounds act as tridentate ligands with the formation of mononuclear complexes Zn(L)Cl2 (CIF files CCDC nos. 2352630 (I) and 2352631 (II)). The absolute quantum yield (QY = 12%) and fluorescence lifetime (τ = 2.64 ns) are measured for complex II containing the pyridine cycle as the azine fragment.

About the authors

Yu. O. Edilova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Yekaterinburg, Russia

Yu. S. Kudyakova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Yekaterinburg, Russia

M. S. Valova

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Yekaterinburg, Russia

N. V. Loseva

Ural Federal University named after the first President of Russia B. N. Yeltsin

Email: email@example.com
Yekaterinburg, Russia

P. A. Slepukhin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B. N. Yeltsin

Yekaterinburg, Russia; Yekaterinburg, Russia

V. I. Saloutin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Yekaterinburg, Russia

D. N. Bazhin

Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B. N. Yeltsin

Email: dnbazhin@gmail.com
Yekaterinburg, Russia; Yekaterinburg, Russia

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