Peculiarities of the synthesis and structures of heterometallic carboxylate complexes with {Zn2Ln} and {Zn2Ca} metal cores

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Abstract

The results of investigation of the heterometallic trinuclear {Zn2Ln} and {Zn2Ca} carboxylate coordination compounds are systematized in the review. The methods of the synthesis, structural peculiarities, and some physicochemical properties are discussed.

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About the authors

S. N. Melnikov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
Moscow

I. K. Rubtsova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
Russian Federation, Moscow

S. A. Nikolaevskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: sanikol@igic.ras.ru
Russian Federation, Moscow

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
Russian Federation, Moscow

M. A. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: sanikol@igic.ras.ru
Russian Federation, Moscow

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Supplementary files

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2. Fig. 1. Distribution diagram of rare earth element complexes with a metal core {Zn2Ln} by lanthanides in publications for the period from 2001 to 2023.

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3. Fig. 2. 3D conformations of the resulting complexes from publication [89] (reproduced with modifications with permission of the American Chemical Society, Copyright ©2009, American Chemical Society).

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4. Scheme 1

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5. Scheme 2

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6. Scheme 3

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14. Scheme 11

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