Email this article Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure
- Authors: Skabitskii I.V.1, Shapovalov S.S.1
-
Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 50, No 2 (2024)
- Pages: 138-144
- Section: Articles
- URL: https://rjeid.com/0132-344X/article/view/667622
- DOI: https://doi.org/10.31857/S0132344X24020087
- EDN: https://elibrary.ru/ORENPO
- ID: 667622
Cite item
Open Access
Access granted
Abstract
The reaction of TpReOCl(StBu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(μ-StBu)]2(μ-S2) (I). Complex I can also be synthesized by the reaction of TpReO(StBu)2 with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]2(μ-S2)(μ-S) (II) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex I with dichloromethane containing the molecules with different conformations of the Re2S2 fragment (Ia and Ib) and complex II are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for Ia, Ib, and II, respectively).
Full Text
About the authors
I. V. Skabitskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: skabitskiy@gmail.com
Russian Federation, Moscow
S. S. Shapovalov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: skabitskiy@gmail.com
Russian Federation, Moscow
References
- Trofimenko S. // Chem. Rev. 1993. V. 93. P. 943.
- Lail M., Pittard K. A., Gunnoe T. B. // Adv. Organomet. Chem. 2008. V. 56. P. 95.
- Tisato F., Bolzati C., Duatti A. et al. // Inorg. Chem. 1993. V. 32. № 10. P. 2042.
- Doonan C. J., Nielsen D. J., Smith P. D. et al. // J. Am. Chem. Soc. 2006. V. 128. Р. 305.
- McWhinnie S.L.W., Jones C. J., McCleverty J.A. et al. // Polyhedron. 1993. V. 12. P. 3743.
- Wei L.-P., Ren Z.-G., Zhu L.-W.et al.// Inorg. Chem. 2011. V. 50. P. 4493.
- Y. Arikawa, Y. Otsubo, T. Nakayama et al. // Inorg. Chim. Acta. 2019. V. 490. P. 45.
- Skabitskii I. V., Sakharov S. G., Pasynskii A. A. et al. // Russ. J. Coord. Chem. 2019. V. 45. P. 539. https://doi.org/10.1134/S1070328419080086
- SADABS (version 2008/1). Madison (WI, USA): Bruker AXS Inc., 2008.
- Sheldrick G. M. TWINABS (version 2012/1). Madison (WI, USA): Bruker AXS Inc., 2012.
- Sheldrick G. M. // Acta Crystallogr. A. 2008. V. 64. P. 112.
- Dolomanov O. V., Bourhis L. J., Gildea R. J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339.
- Neese F. The ORCA Program System. Wiley Interdisciplinary Reviews – Computational Molecular Science. 2012. V. 2. P. 73.
- Perdew J. P., Burke K., Ernzerhof M. // Phys. Rev. Lett. 1996. V. 77. P. 3865.
- Perdew J. P., Burke K., Ernzerhof M. // Phys. Rev. Lett. 1997. V. 78. P. 1396 (Errata).
- Weigend F., Ahlrichs R. // Phys. Chem. Chem. Phys. 2005. V. 7. P. 3297.
- Grimme S., Ehrlich S., Goerigk L. // J. Comput. Chem. 2011. V. 32. P. 1456.
- Grimme S., Antony J., Ehrlich S. et al. // J. Chem. Phys. 2010. V. 132. P. 154104.
- Adamo C., Barone V. // J. Chem. Phys. 1999. V. 110. P. 6158.
- van Lenthe E., Baerend E. J., Snijders J. B. // J. Chem. Phys. 1993. V. 99. P. 4597.
- van Wüllen C. // J. Chem. Phys. 1998. V. 109. P. 392.
- Rolfes J. D., Neese F., Pantazis D. A. // J. Comput. Chem. 2020. V. 41. P. 1842.
- Pantazis D. A., Chen X. Y., Landis C. R. et al. // J. Chem. Theory Comput. 2008. V. 4. P. 908.
- Diemann E., Muller A. // Z. Naturforsch. B. 1976. V. 31. P. 1287.
- Cordero B., Gómez V., Platero-Prats A.E. // Dalton Trans. 2008. V. 21. P. 2832.
- Goodman J. T., Rauchfuss T. B. // Inorg.Chem. 1998. V. 37. P. 5040.
- Gourlay C., Taylor M. K., Smith P. D. et al. // Inorg. Chim. Acta. 2010. V. 363. P. 1126.
Supplementary files
