Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate

I. F. Sakhapov; Сахапов И. Ф.; A. A. Kagilev; Кагилев А. А.; A. O. Kantyukov; Кантюков А. О.; I. K. Mikhailov; Михайлов И. К.; O. S. Sof’icheva; Софьичева О. С.; D. R. Islamov; Исламов Д. Р.; Z. N. Gafurov; Гафуров З. Н.; D. G. Yakhvarov; Яхваров Д. Г.

doi:10.31857/S0044457X23601098

Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate

作者: Sakhapov I.F.¹, Kagilev A.A.¹^,2, Kantyukov A.O.¹^,2, Mikhailov I.K.¹^,2, Sof’icheva O.S.¹, Islamov D.R.³, Gafurov Z.N.¹, Yakhvarov D.G.¹^,2
隶属关系:
1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
2. Alexander Butlerov Institute of Chemistry, Kazan Federal University
3. Laboratory for Structural Analysis of Biomacromolecules, FRC Kazan Scientific Center, Russian Academy of Sciences
期: 卷 68, 编号 9 (2023)
页面: 1287-1292
栏目: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjeid.com/0044-457X/article/view/666263
DOI: https://doi.org/10.31857/S0044457X23601098
EDN: https://elibrary.ru/WOIXFC
ID: 666263

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详细

New bis-chelate cobalt(II) complex [Co(DPG)2(DMF)2] (1), where DPG is N-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex 1 has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
= –1.70 V vs Ag/AgNO3, 1 × 10–2 М in CH3CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.

关键词

α-phosphino-α-amino acid, α-diphenylphosphorylglycinate, cobalt complex, X-ray diffraction, cyclic voltammetry

参考

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