Thermal Conductivity of Cesium Bismuthides in the Liquid State

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The thermal conductivity of liquid alloys of the cesium–bismuth system with 20–66 at % Bi in the temperature range from the liquidus line to 1173 K has been studied experimentally with an error of 4–6%. It was found that the thermal conductivity of liquid cesium bismuthides for the indicated compositions and temperatures takes low values from 0.7 to 4.5 W/(m K) typical for liquid salts. The thermal diffusivity and Lorenz number were calculated from the results of thermal conductivity measurements. An analysis of the temperature and concentration dependences of the studied properties indirectly confirms current views on the presence of ordered structures called ionic complexes in alkali metal bismuthide melts, which significantly affect the thermophysical properties of melts and are destroyed at elevated temperatures.

Авторлар туралы

A. Agazhanov

Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences

Email: scousekz@gmail.com
630090, Novosibirsk, Russia

R. Abdullaev

Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences

Email: scousekz@gmail.com
630090, Novosibirsk, Russia

A. Khairulin

Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences

Email: scousekz@gmail.com
630090, Novosibirsk, Russia

S. Stankus

Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: scousekz@gmail.com
630090, Novosibirsk, Russia

Әдебиет тізімі

  1. Самсонов Г.В., Абдусалямова М.Н., Черногоренко В.Б. Висмутиды. Киев: Наукова думка, 1977. 138 с.
  2. Королева О.С., Чулков Е.В. // ФТП. 1992. Т. 26. № 2. С. 223.
  3. van der Lugt W. // Phys. Scr. 1991. V. 1991. № T39. P. 372. https://doi.org/10.1088/0031-8949/1991/T39/059
  4. Petric A., Pelton A.D., Saboungi M.-L. // J. Electrochem. Soc. 1988. V. 135. № 11. P. 2754. https://doi.org/10.1149/1.2095424
  5. Meijer J.A., van der Lugt W. // J. Phys. Condens. Matter. 1989. V. 1. № 48. P. 9779. https://doi.org/10.1088/0953-8984/1/48/024
  6. Xu R., Kinderman R., van der Lugt W. // J. Phys. Condens. Matter. 1991. V. 3. № 1. P. 127. https://doi.org/10.1088/0953-8984/3/1/010
  7. Steinleitner G., Freyland W., Hensel F. // Ber. Bunsenges. Phys. Chem. 1975. V. 79. № 12. P. 1186. https://doi.org/10.1002/bbpc.19750791204
  8. Хайрулин Р.А., Абдуллаев Р.Н., Станкус С.В. // Журн. физ. химии. 2017. Т. 91. № 10. С. 1719. Khairulin R.A., Abdullaev R.N., Stankus S.V. // Russ. J. Phys. Chem. A. 2017. V. 91. № 10. P. 1946. https://doi.org/10.1134/S0036024417100181
  9. Stankus S.V., Abdullaev R.N., Khairulin R.A. // High Temp-High Press. 2018. V. 47. № 5. P. 403.
  10. Khairulin R.A., Stankus S.V., Abdullaev R.N. // J. Eng. Thermophys. 2018. V. 27. № 3. P. 303. https://doi.org/10.1134/S1810232818030050
  11. Khairulin R.A., Abdullaev R.N., Stankus S.V. // Phys. Chem. Liq. 2020. V. 58. № 2. P. 143. https://doi.org/10.1080/00319104.2018.1553042
  12. Агажанов А.Ш., Абдуллаев Р.Н., Самошкин Д.А., Станкус С.В. // Журн. физической химии. 2021. Т. 95. № 7. С. 971. Agazhanov A.S., Abdullaev R.N., Samoshkin D.A., Stankus S.V. // Russ. J. Phys. Chem. A. 2021. V. 95. № 7. P. 1291. https://doi.org/10.1134/S0036024421070037
  13. Agazhanov A.Sh., Abdullaev R.N., Samoshkin D.A., Stankus S.V. // Fusion Engineering and Design. 2020. V. 152. № 111456. P. 1. https://doi.org/10.1016/j.fusengdes.2020.111456
  14. Станкус С.В., Савченко И.В., Яцук О.С., Козловский Ю.М. // Теплофизика и аэромеханика. 2018. Т. 25. № 4. С. 665. Stankus S.V., Savchenko I.V., Yatsuk O.S., Kozlovskii Y.M. // Thermophysics and Aeromechanics. 2018. Т. 25. № 4. С. 639. https://doi.org/10.1134/S0869864318040170
  15. Савченко И.В., Станкус С.В., Агажанов А.Ш. // ТВТ. 2013. Т. 51. № 2. С. 314. Savchenko I.V., Stankus S.V., Agazhanov A.Sh. // High Temp. 2013. V. 51. № 2. P. 281. https://doi.org/10.1134/S0018151X13010148
  16. Agazhanov A.S., Abdullaev R.N., Samoshkin D.A., Stankus S.V. // High Temp–High Press. 2018. V. 47. № 4. P. 311.
  17. An X., Cheng J., Yin H. et al. // Int. J. Heat Mass Transf. 2015. V. 90. P. 872. https://doi.org/10.1016/j.ijheatmasstransfer.2015.07.042
  18. Агажанов А.Ш., Абдуллаев Р.Н., Самошкин Д.А., Станкус С.В. // Теплофизика и аэромеханика. 2017. Т. 24. № 6. С. 955. Agazhanov A.Sh., Abdullaev R.N., Samoshkin D.A., Stankus S.V. // Thermophysics and Aeromechanics. 2017. V. 24. № 6. P. 927. https://doi.org/10.1134/S0869864317060117
  19. Hochgesand K., Winter R. // J. Chem. Phys. 2000. V. 112. № 17. P. 7551. https://doi.org/10.1063/1.481328
  20. van der Aart S.A., Verhoeven V.W.J., Verkerk P. // J. Chem. Phys. 2000. V. 112. № 2. P. 857. https://doi.org/10.1063/1.480612

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу
2.

Жүктеу (102KB)
Метадеректер
3.

Жүктеу (90KB)
Метадеректер
4.

Жүктеу (51KB)
Метадеректер

© А.Ш. Агажанов, Р.Н. Абдуллаев, А.Р. Хайрулин, С.В. Станкус, 2023