Email this article Conditions for formation of structure of porous hybrid materials from cellulosic fabric and macromolecular N-substituted cyclic aminoacetates with grafted aerosil microparticles
- Authors: Kobrin M.R.1,2, Tsivadze A.Y.1,2, Fridman A.Y.1, Khairutdinova D.R.3, Burova A.Y.4, Babaitsev A.V.4, Bulychev N.A.1,4
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Affiliations:
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
- MIREA – Russian Technological University
- A. A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
- Moscow Aviation Institute (National Research University)
- Issue: Vol 99, No 5 (2025)
- Pages: 759-762
- Section: PHYSICAL CHEMISTRY OF DISPERSED SYSTEMS AND SURFACE PHENOMENA
- Submitted: 22.09.2025
- Published: 15.12.2025
- URL: https://rjeid.com/0044-4537/article/view/691148
- DOI: https://doi.org/10.31857/S0044453725050101
- EDN: https://elibrary.ru/hfcnrb
- ID: 691148
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Abstract
The stagesof synthesis of porous hybrid material from cellulose fabric andmacromolecular N-substituted cyclic aminoacetates with grafted aerosil microparticles are studied.Such a structure is found to be formed if thecellulose fibers are filled with a suspension of agglomerates ofaerosil particles in PVC shells, the diameter of which isgreater than the width of the gaps between the microfibrilribbons. Ribbons and fibrils are cross-linked by grafting PVC macromoleculessimultaneously to cellulose on the surface of the ends andto the surface of the aerosil particles. The frameworks arestrengthened and the porous structure is formed as linear PVCmacromolecules grafted to cellulose and to aerosil are transformed intocyclic amine structures.
About the authors
M. R. Kobrin
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences; MIREA – Russian Technological University
Email: kobrin92@ya.ru
Moscow, 119071 Russia; Moscow, Russia
A. Yu. Tsivadze
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences; MIREA – Russian Technological University
Email: kobrin92@ya.ru
Moscow, 119071 Russia; Moscow, Russia
A. Ya. Fridman
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: kobrin92@ya.ru
Moscow, 119071 Russia
D. R. Khairutdinova
A. A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Email: kobrin92@ya.ru
Moscow, 119334 Russia
A. Yu. Burova
Moscow Aviation Institute (National Research University)
Email: kobrin92@ya.ru
Moscow, 125993 Russia
A. V. Babaitsev
Moscow Aviation Institute (National Research University)
Email: kobrin92@ya.ru
Moscow, 125993 Russia
N. A. Bulychev
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences; Moscow Aviation Institute (National Research University)
Author for correspondence.
Email: kobrin92@ya.ru
Moscow, 119071 Russia; Moscow, 125993 Russia
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