Enviar artigo por via de e-mail Features of the Synthesis of Few-Layer Phosphorene Structures During Plasma Electrochemical Cleavage of Black Phosphorus
- Autores: Kochergin V.K.1, Manzhos R.A.1, Komarova N.S.1, Kotkin A.S.1, Krivenko A.G.1, Krushinskaya I.N.2, Pelmenyov A.A.2
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Afiliações:
- Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences
- Branch of N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
- Edição: Volume 58, Nº 3 (2024)
- Páginas: 216-220
- Seção: PLASMA CHEMISTRY
- URL: https://rjeid.com/0023-1193/article/view/661347
- DOI: https://doi.org/10.31857/S0023119324030069
- EDN: https://elibrary.ru/UUGJUA
- ID: 661347
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Resumo
A comparative study of the emission spectra of cathode electrolysis plasma during plasma electrochemical cleavage of black phosphorus and graphite under maximally identical experimental conditions has been carried out. A significantly lower concentration of active intermediates (OH radicals and O atoms) in the electrolysis plasma during the cleavafe of black phosphorus was found compared with a graphite electrode. It is assumed that this effect is due to a significantly higher rate of interaction of these intermediates with synthesized phosphorene structures than with graphene-like particles. This is confirmed by the detection of a much higher oxygen content in the products of black phosphorus cleavage than in synthesized carbon nanoparticles.
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Sobre autores
V. Kochergin
Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
R. Manzhos
Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
N. Komarova
Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
A. Kotkin
Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
A. Krivenko
Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
I. Krushinskaya
Branch of N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
A. Pelmenyov
Branch of N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: kochergin@icp.ac.ru
Rússia, Chernogolovka
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